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CIPDBChina IndustryChemicalsChemical Auxiliary & Catalyst



Silane Coupling Agent Series for Tyre Manufactures and Rubber Industries1

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Chemical Auxiliary CatalystSilane Coupling Agent SeriesSilane Coupling Agent

Shanghai Limwell New Material Tech.Co., Ltd.

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Product Description Product DescriptionSilane Coupling Agent SeriesComposition:Structural formula: Use the classic structure as:Y(CH2)nSi(OR)3OR in the figure refers to the hydrolysable group-Alkoxy,for example, methoxy,ethoxy. The alkoxy group can react with the added or residual water on the surface of the inorganic substance to hydrolyze into a hydroxyl group, and then these hydroxyl groups will undergo condensation reaction with the hydroxyl group on the surface of the inorganic substance to remove a water molecule and form a strong chemical bond. Y in the figure refers to an organic functional group.such as amino, methacryloxy, epoxy, vinyl.mercapto, etc :Different organic functional groups are suitable for different organic polymers. It can chemically react with the polymer (thermosetting) or form a physical entanglement or interpenetrating network system (thermoplastic) to form a strong chemical bond.Packing:25L/ barrel or 200L/barrelPerformance and Application:1,Silane coupling agents have unique chemical and physical properties, which not only enhance the bond strength, but more importantly,prevent the bond dissociation on the interface of the composite material during aging and use.2.The coupling agent gives the ability to bind stably between two different difficult to bond surfaces. In composite materials, choosing the right silane can greatly increase the bending strength (tensile strength and modulus) of the composite material,while enhancing the material's resistance to humidity and other vicious environmental conditions. 3,Other advantages that silane coupling agents can provide include:  Better wetting properties of resin  Anti-humidity and dewatering agent  Building waterproof  Better dispersibility of mineral fillers  Make plastic clearer and transparentUsage:1.It can be used to bond inorganic fillers and plastics to polymers,optimize polypropylene manufacturing. crosslink polyethylene, and produce thermoplastic vulcanizates (TPVS).2.It also be used to produce white carbon black reinforced rubber for "green" tires.The reaction mechanism of silane on inorganic materialsSilane coupling agents containing three inorganic reactive groups (usually methoxy, ethoxy or acetyl) on the silicon atom can bind the metal hydroxyl groups of most inorganic materials well , especially the structure contains silicon, aluminum or heavy metal materials. By reacting with added or residual water on the inorganic surface, the siloxy group on the silicon atom is hydrolyzed into silanol, and then the silanol reacts with the metal hydroxyl on the inorganic surface to form an alkoxy structure and remove water. Silanes can also be combined with each other to form a multi-molecular structure of the silane coupling agent, usually more than one layer or equivalent of silane is used on the surface, this will form a dense siloxane layer on the surface of the inorganic material and make the inorganic surface farther away from the interface.Mechanism of action on silane coupling agentsReaction mechanism of silane to polymerThe combination of silanes to organic polymers is very complicated The reactivity of the thermosetting polymer should match the reactivity of the silane. For example,epoxy silane or amino silane will combine with epoxy resin,amino silane will combine with phenolic resin,the methacrylic silane will combine with styrene cross-linked the unsaturated polyester resin.For thermoset polymers whose reactivity plays an important role, the matching of chemical structures will improve the physical properties of composite materials. The reaction of silane and resin generally has the following three forms:1.Graft2.Chemical bond3.CopolymerizationFor thermoplastic polymers, the bonding achieved by the silane coupling agent can be interpreted as the formation of inter-diffusion and interpenetrating network systems in the interface region Therefore,for thermoplastic resin, the compatibility of silane and resin is very important. Matching the solubility parameters of the two materials will help increase the probability of forming practical composite with the best performance.1.Chlorosilane IntermediateTechnical Parameters:Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-Z13-Chloropropyltrichlorosilane2250-06-3    Intermediate, filled composite materialsLW-Z23-Chloropropyltrimet hoxysilane2530-87-2Z-6076CPTMOKBM-703 Intermediate, silicone rubberLW-Z33-Chloropropyltriet hoxysilane5089-70-3Z-6376CPTEOKBE-703 Intermediate, silicone rubberLW-Z4Trimethoxysilane2487-90-3    IntermediateLW-Z53-ChloropropylmethyIdichlorosilane7787-93-1    IntermediateLW-Z63-ChloropropylmethyIdimethoxysilane18171-19-2  KBE-702A-133Intermediate, silicone rubberLW-Z73-ChloropropylmethyIdiethoxysilane13501-76-3 CPMDEOKBE-702 Intermediate,silicone rubberLW-Z83-Propyltrichlorosilane141-57-1Z-1213PTCS  Intermediate,Filled composite materials2.Alkyl Silane Technical Parameters:Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-W311Methyltrimethoxysilane1185-55-3Z-6070MTMSKBM-13A-1630filed composite materials,waterproof,resin,adhesives,coatingsLW-W321Methyltriethoxysilane2031-67-6Z-6370MTESKBE-13A-162filled composite materials,waterproof,resin,adhesives,coatingsLW-W313n-Propytrimethoxysilane1067-25-0Z-6264PTMOKBM-3033 filled composite materials,waterproof,resin,adhesives.coatingsLW-W323n-Propyltriethoxysilane2550-02-91-6535PTEOKBE-30335025filled composite materials,waterproof,resin,adhesives,coatingsLW-W318n-Octyltrimethoxysilane3069-40-7Z-6665OCTMO  filled composite materials,waterproof,resin,adhesives,coatingsLW-W3181isO-octyltrimethoxysilene34396-03-7Z-6672   filled composite materials,waterproof,resin,coatingsLW-W328n-Octyltriethoxysilane2943-75-1Z-6341OCTEO A-137filled composite materials,waterproof,resin,coatingsLW-W3281iso-Octyltriethoxysilane35435-21-3    filled composite materials,waterproof,resin,coatingsLW-W3112n-Dodecyltrimethoxysilane3069-21-4 DOTMO  filled composite materials,waterproof,resinLW-W3116n-Hexadecyltrimethoxysilane16415-12-6 9116 HDTMSfilled composite materials,waterproof,resin  3.Sulfur Silane Technical Parameters:Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-YG69Bis[3-(triethoxysilyl)propyl]tetrasulfide40372-72-3Z-6940Si69KBE-846A-1289tires,rubber,silicone rubberLW-GG69Bis[3-(triethoxysilyl)propy]tetrasulfide(50%)and Carbon black(50%)N.AZ-6945X50-S  tires,rubberLW-YG75Bis[3-(triethoxysilyl)propy]disulfide56706-10-6Z-6920Si75KBE-886BA-1589tires,rubber,silicone rubberLW-GG75Bis[3-(triethoxysilyl)propY]disulfide(50%)and Carbon black(50%)N.AZ-6925x266-S  tires,rubberLW-Q189Mercaptopropyltrimethoxysilane4420-74-0Z-6062MTMOKBM-803A-189rubber,plastics,glass fiber,coatingsLW-Q18913-Mercaptopropyltriethoxysilane14814-09-6Z-6911Si 263KBE-803A-1891rubber,plastics,glass fiber,coatingsLW-Q2643-Thiocyanatopropyltriethoxysilane34708-08-2 Si 264  rubber,silicone rubber 4.Amino Silane Technical Parameters:Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-A5203-Aminopropylmethyldiethoxysilane3179-76-8Z-60151505KBE-902A-2100textile,glass fiber, filled composite materials,adhesives,coatingsLW-A5303-Aminopropylmethyldlmethoxysilane3663-44-3  KBM-902A-2110glass fiber,filled composite materials,castings,adhesives,coatingsLW-A5403-Aminopropyltrimethoxysilane13822-56-5Z-6610AMMOKBM-903A-1110glass fiber,filled composite materials,castings,adhesives,coatingsLW-A5503-Aminopropyltriethoxysilane919-30-2Z-6011AMEOKBE-903A-1100glass fiber,filled composite materials, castings,rubber,resin, plastics,adhesives,coatingsLW-A550G3-Aminopropyltriethoxysilane919-30-2   A-1102glass fiber,filed composite materials, castings,rubber,resin,plastics,adhesives, coatingsLW-A602N-(2-Aminoethyl)-3-aminopropylmethyldimethoxysilane3069-29-2Z-64361411KBM-602A-2120filled composite materials,castings,adhesives,coatingsLW-A791N-(2-Aminoethyl)-3aminopropyltriethoxysilane5089-72-5Z-6021 KBE-603 filled composite materials,castings,resin,adhesives,coatingsLW-A792N-(2-Aminoethyl)-3-aminopropyltrimethoxysilane1760-24-3Z-6020DAMOKBM-603A-1120(98%)glass fiber,filled composite materials , castings , resin, plastics,adhesives,coatingsLW-A792GN-(2-Aminoethyl)-3-aminopropyltrimethoxysilane1760-24-3 DAMO-T A-1120(85%)glass fiber,filled composite materials , castings,resin, plastics,adhesives,coatingsLW-A1163-Ureidopropytrimethoxysilane23843-64-3   A-1524filled composite materials,castings,adhesives,coatingsLW-A11613-Ureidopropyltriethoxysilane(50%methanol)23779-32-0Z-66792201KBE-585A-1160filled composite materials,castings,resin,adhesives,coatingsLW-A117Bis[3-trimethoxysilyl)propyl]amine82985-35-1 1124 A-1170glass fiber,filled composite materials,adhesives,coatingsLW-A1171Bis[3-triethoxysilyl)propyl]amine13497-18-2 1122  glass fiber,filled composite materials,adhesives,coatingsLW-A1183-(Phenylamino)propyltrimethoxysilane3068-76-6Z-6083 KBE-573Y-9669filled composite materials,castings,resin,adhesives,coatingsLW-A1189N-(n-Butyl)-3-aminopropyltrimethoxysilane31024-56-3 1189  textile,glass fiber, filled composite materials,adhesives,coatings 5.Phenyl Silane  Technical Parameters: Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-B31Phenyltrimethoxysilane2996-92-1Z-61249165KBM-103A-153resin,Silicone oilLW-B32Phenyltriethoxysilane780-69-8Z-98059265KBE-103 resin,Silicone oilLW-B21Diphenyldimethoxysilane6843-66-9AY43-0476010KBM-202SS resin,Silicone oilLW-B22Diphenyldiethoxysilane2553-19-71-6533 KBE-202 resin,Silicone oil 6.Acyl Silane  Technical Parameters: Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-X5703-Methacryloyloxypropyltrimethoxysilane2530-85-0Z-6030MEMOKBM-503A-174glass fiber,filled composite materials,resin,adhesives,coatingsLW-X5713-Methacryloyloxypropyltriethoxysilane21142-29-0Z-6036 KBE-503Y-11878glass fiber .filled composite materials,resin,adhesivesLW-X5723-Methacryloyloxypropylmethyldimethoxyslane14513-34-9Z-6033 KBM-502 glass fiber , filled composite materials,resin,adhesives 7.Epoxy Silane Technical Parameters:Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-H1862-(3,4Epoxycyclohexyl)ethyl]trimethonxysilane3388/4/3Z-6043 KBM-303A-186glass fiber,resin, sealants,coatings,castingsLW-H5603-Glycidyloxypropyltrimethoxysilane2530-83-8Z-6040GLYMOKBM-403A-187glass fiber,filled composite materials, resin, adhesives,coatingsLW-H5613-Glycidyloxypropyltriethoxysilane2602-34-8Z-6041GLYEOKBE-403A-1871glass fiber, filled composite materials,resin,coatingsLW-H5623-Slycidyloxypropylmethyldimethoxysilane65799-47-5Z-6044 KBM-402 glass fiber ,filed composite materials,resin,coatingsLW-H5633-Glycidyloxypropylmethyldiethoxysilane2897-60-1Z-6042 KBE-402Wetlink 78glass fiber ,filled composite materials,resin,coatings 8.Vinyl Silane  Technical Parameters:Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-Y150Vinyltrichlorosilane75-94-5    IntermediateLW-Y151Vinyltriethoxysilane78-08-0Z-6518VTEOKBE-1003A-151cables,glass fiber, filled composite materials,resin,adhesives,coatingsLW-Y171Vinyltrimethoxysilane2768-02-7Z-6300VTMOKBM-1003A-171cables,glass fiber,filled composite materials,resin,adhesives,coatingsLW-Y172Vinyltris(2-methoxyethoxy)silane1067-53-4Z-6172VTMOEOKBC-1003A-172cables,glass fiber,filled composite materials,resin,adhesives,coatingsLW-Y173Vinyltri(isopropoxy)siane18023-33-1Z-6550  CoatOsil1706cables,glass fiber,resin,coatingsLW-Y2171Vinylmethyldimethoxysilane16753-62-1    silicone rubber,silicone resin9.Silicate Technical Parameters:Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-Si22Tetrapropoxysilane682-01-9    filled composite materials ,resin,coatings,rubberLW-Si28Tetraethoxysilane78-10-4Z-6697DYNASILAKBE-04TEOSfilled composite materials,castings, rubber,resin,adhesives,coatings,aerogelLW-Si32Ethyl Siicate-32NA DYNASIL32  filled composite materials,castings, rubber,resin,adhesives,coatingsLW-Si39Methylorthosilicate681-84-5    coatings,silicone rubberLW-Si40Ethyl Silicate-4018954-71-7 DYNASIL 40 TEOS-40filled composite materials,castings, rubber,resin,adhesives,coatings10.lsocyanato Silane Technical Parameters:Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-YQ353-lsocyanatopropyltrimethoxysilane15396-00-6   A-LINK35sealants,resin modification,crosslinking agentLW-YQ253-lsocyanatopropyltriethoxysilane24801-88-5   A-UINK25sealants,resin modification,crosslinking agent11.Others Technical Parameters:Product brandEnglish chemical nameCAS#Reference brandApplication fieldDow corningEvonikShinEtsuMomentiveLW-F21H,1H,2H,2H-perfluoroalkyltriethoxysilane51851-37-7 F8261  glass,stone,coatingsLW-CV4Tetramethyltetravinylcyclotetrasiloxane2554-6-5My-CYC-4   silicone oil,silicone rubberNew products are being developed, and can be customized. Silane Selection Guide Company ProfileLimwell New Material Tech. In 2013, Shanghai Limwell New Material Tech. Co., Ltd. started the operation in Shanghai, China, Limwell is an export-oriented comprehensive company, dedicating efforts mainly on the manufacturing and trading of rubber aidditives and tyre-specific materials.Our manufacturing base are at Shan-dong and Zhe-jiang provinces of China.In addition to that, we have also built partnership with a number of China local plants to enrich our product family. Our products includes processing additives, Anti-ozone waxes, masterbatches, resins, peroxides, flameretarders, and a widespectrum of other materials used in tyre and rubber products.With the belief in mind to provide both trusted product quality and outstanding sales service, we have become the stable supplier for a great number of tyre and rubber products plants all around the world. We uphold the concept "quality goes first, in service we trust, human oriented and sustainable development", willing to be the best fit partner on your way to success!  Our  Plant One of our plants is located in the Zheshang Science and Technology Park at Jiashan, Zhejiang. This plant is at the center of prosperous Jiangsu-Zhejiang-Shanghai economic zone, and has achieved fast and sustainable growth since the establishment due to strong market demand and our outstanding research and quality control capabilities. This plant can provide high quality masterbatches, homoginizer, vulcanizer, scorch retarder and several other rubber processing additives. In 2014,we passed the lS09001 and IS014001 Certification  audit.In 2016,we passed the TS16949 Quality System and OHSAS 18001 certification audit. In the fast development procedure, we have also paid attention to operate in a sustainable and environment friendly manner, strictly adhering to the national and local environment protection regulations. 

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